BiI3 has a common structural
arrangement shared by many halides of the transition metals
with formula MX3. It has a hexagonal close packed array
of iodide ions with Bi(III) sitting in 1/3 of the octahedral sites
and between adjacent layers of I's. Highlight the hcp (ABABAB) layers of I's Show 2nd layer of I's Show 3rd layer of I's Show 2nd and 3rd layer Show 2nd and 4th layer Highlight a Bi site, CN=6 Highlight a I site, CN=2 wireframe Reset Complexes that adopt this structure include.. TiCl3, TiBr3, CrBr3, FeCl3, FeBr3. |
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Created and maintained by Prof. Robert J. Lancashire,