Bismuth Iodide - BiI3

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BiI3 has a common structural arrangement shared by many halides of the transition metals with formula MX3. It has a hexagonal close packed array of iodide ions with Bi(III) sitting in 1/3 of the octahedral sites and between adjacent layers of I's.
Highlight the hcp (ABABAB) layers of I's
Show 2nd layer of I's
Show 3rd layer of I's
Show 2nd and 3rd layer
Show 2nd and 4th layer

Highlight a Bi site, CN=6
Highlight a I site, CN=2

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Complexes that adopt this structure include..
TiCl3, TiBr3, CrBr3, FeCl3, FeBr3.
Information is available to show how the individual structural pages were created.
Return to the structure of binary salts introductory page.

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Copyright © 2006 by Robert John Lancashire, all rights reserved.

Created and maintained by Prof. Robert J. Lancashire,
The Department of Chemistry, University of the West Indies,
Mona Campus, Kingston 7, Jamaica.
Created March 2000. Links checked and/or last modified 17th June 2006.
URL http://wwwchem.uwimona.edu.jm/courses/bii3J.html