CHEM1902 Main Group Chemistry
Tutorial 3 - 2015
Prof Robert J. Lancashire
Muliple Choice Questions
1. In which of the following reactions is H2O2 not acting as an oxidizing agent?
a) 2Fe2+ + H2O2 + 2H+ → 2Fe3+ + 2H2O
b) PbS + 4H2O2 → PbSO4 + 4H2O
c) 2I- + 2H2O2 + 2H+ → I2 + 2H2O
d) Mn2+ + H2O2 + 2OH- → MnO2 + 2H2O
e) Ag2O + 2H2O2 → 2Ag + O2 + H2O
Short Answer Questions
- You are provided with two liquids, one is H2O and the other
is H2O2. Safety regulations now prohibit you from
touching/tasting them so suggest chemical tests that could distinguish between
them. Include the reagents and observations expected and show balanced
equations for the reactions.
-
Use the MO diagram below to determine the bond order for the following species
and predict whether the bond lengths shown are consistent with your values.
|
O2+ = 112 pm
O2 = 121 pm
O2- = 128 pm
O22- = 149 pm
|
- With the aid of suitable equations describe how H2O2
can be produced industrially and on a small scale in the laboratory.
- Write balanced half equations and the net ionic equation for:
i) the oxidation of Fe2+ by H2O2 in acidic solution.
ii) the reaction between KMnO4 and H2O2 in acidic solution.
iii) the reaction between acidified KBr and H2O2.
- Describe two uses of D2O, including the chief large scale use.
- With the aid of equations, describe how ozone is produced and destroyed
in the upper atmosphere.
- How would you prepare ozone in the laboratory? What conditions and
safety equipment would be needed?
- What experiment/techniques could be used to distinguish between O3
and O2?
- How does the O-O bond length in O3 of 127.2 pm compare to the
data above for O2 species?
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Lancashire, all rights reserved.
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Lancashire,
The Department of Chemistry, University of the West Indies,
Mona Campus, Kingston 7, Jamaica.
Created November 2014. Links checked and/or last
modified 16th February 2015.
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