CHEM1902 Main Group Chemistry
Tutorial 3 - 2015
Prof Robert J. Lancashire
Muliple Choice Questions
1. In which of the following reactions is H2O2 not acting as an oxidizing agent?
a) 2Fe2+ + H2O2 + 2H+ → 2Fe3+ + 2H2O
b) PbS + 4H2O2 → PbSO4 + 4H2O
c) 2I- + 2H2O2 + 2H+ → I2 + 2H2O
d) Mn2+ + H2O2 + 2OH- → MnO2 + 2H2O
e) Ag2O + 2H2O2 → 2Ag + O2 + H2O
Short Answer Questions
- You are provided with two liquids, one is H2O and the other 
is H2O2. Safety regulations now prohibit you from 
touching/tasting them so suggest chemical tests that could distinguish between 
them. Include the reagents and observations expected and show balanced 
equations for the reactions.
 
- 
Use the MO diagram below to determine the bond order for the following species 
and predict whether the bond lengths shown are consistent with your values.
 
 | 
O2+ = 112 pm 
O2 = 121 pm 
O2- = 128 pm 
O22- = 149 pm 
 | 
 
 
- With the aid of suitable equations describe how H2O2 
can be produced industrially and on a small scale in the laboratory.
  
- Write balanced half equations and the net ionic equation for:
i) the oxidation of Fe2+ by H2O2 in acidic solution.
							
ii)	the reaction between KMnO4 and H2O2 in acidic solution.
				
iii) the reaction between acidified KBr and H2O2. 
- Describe two uses of D2O, including the chief large scale use.
  
- With the aid of equations, describe how ozone is produced and destroyed 
in the upper atmosphere.
 
- How would you prepare ozone in the laboratory?	What conditions and 
safety equipment would be needed?
 	 	
- What experiment/techniques could be used to distinguish between O3 
and O2?
 
- How does the O-O bond length in O3 of 127.2 pm compare to the 
data above for O2 species?
 
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Lancashire,
The Department of Chemistry, University of the West Indies,
 Mona Campus, Kingston 7, Jamaica.
Created November 2014. Links checked and/or last
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